Potassium Permanganate Manufacturers, SDS MSDS Sheet

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Potassium Permanganate Commercial Pure & BP USP ACS IP Manufacturers

Potassium Permanganate
Technical & Pure Crystals
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Potassium Permanganate

Potassium Permanganate SDS MSDS Sheet, Material Safety Data Sheet

1. PRODUCT DESCRIPTION

Product Name: Potassium Permanganate
CAS Number: 7722-64-7
Formula: KMnO4
Synonyms: Permanganic acid, potassium salt

2. HAZARD IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 2
Acute toxicity, oral Category 4
Acute toxicity, dermal Category 4
Serious eye damage/eye irritation Category 2B
Hazardous to the aquatic environment, acute hazard Category 1

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizer
Oxidizing Solid

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Aquatic Toxicity
Aquatic Toxicity

Signal Word: Warning

Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H320: Causes eye irritation.
H400: Very toxic to aquatic life.

Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P302+352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P362: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use dry chemical, CO2 or appropriate foam for extinction.
P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient: Potassium Permanganate
CAS No.: 7722-64-7

4. FIRST AID MEASURES

Emergency and First Aid Procedures:
Eyes - Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention at once.
Ingestion - If Potassium permanganate is swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Keep person warm and quiet, and get medical attention at once.

5. FIREFIGHTING PROCEDURES

Extinguisher Media: Use dry chemical, CO2 or appropriate foam.
Special Firefighting Procedures: Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus.
Unusual Fire and Explosion Hazards: Potassium permanganate is strong oxidizer. Contact with combustible materials, flammable materials or powdered metals can cause fire or explosion.

6. SPILL OR LEAK PROCEDURES

Steps to be Taken in Case Material is Released or Spilled: Ventilate area of spill. Clean-up personnel should wear proper protective equipment. Avoid creating dust. Sweep or scoop up and containerize for disposal.

7. SPECIAL PRECAUTIONS

Precautions to be taken in Handling or Storing: Keep Potassium permanganate container tightly closed.
Other Precautions: Store separately and away from flammable and combustible materials.

8. SPECIAL PROTECTION INFORMATION

Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation.
Respiratory Protection (Specify Type): None needed under normal conditions of use with adequate ventilation.
NIOSH approved equipment should be worn if PELs are exceeded.
Ventilation: Local Exhaust: Yes
Mechanical (General): Yes
Protective Gloves: Rubber, neoprene, PVC, or equivalent.
Eye Protection: Splash proof chemical safety goggles should be worn at all times.
Other Protective Clothing or Equipment: Lab apron, eye wash, and safety shower.
Exposure Limits:
Chemical Name: Manganese and inorganic compounds, as Mn
ACGIH (TLV): TWA : 0.2 mg/m3(A4)
OSHA (PEL)   : STEL: C 5 mg/m3
NIOSH (REL): TWA: 1 mg/m3 / STEL: 3 mg/m3

9. PHYSICAL DATA

Molecular Weight: 158.04
Melting Point: Approximately 240C
Vapor Pressure: N/A
Vapor Density (Air=1): 5.4
Specific Gravity(H2O=1): 2.7
Percent Volatile by Volume: 0 (21C)
Solubility in Water: Moderate
Appearance and Odor: Potassium permanganate is dark purple to bronze crystals, odorless

10. REACTIVITY DATA

Stability: Potassium permanganate is stable
Conditions to Avoid: Heat
Incompatibility (Materials to Avoid): Organic materials, combustible materials, strong reducing agents, strong acids, peroxides, alcohols, chemically active metals.
Hazardous Decomposition Products: None
Hazardous Polymerization: Will not occur.

11. TOXICITY DATA

Toxicity Data: Oral Rat LD50: 750 mg/kg
Carcinogenicity: This substance has no evidence of carcinogenic properties.

12. ECOLOGICAL DATA

EPA Waste Numbers: D001
AQUATIC TOXICITY
LC 50 (Rainbow trout, donaldson trout (Oncorhynchus mykiss), 96 h): 0.267 - 0.442 mg/l Mortality
LC 50 (Striped bass (Morone saxatilis), 96 h): 0.348 mg/l Mortality
LC 50 (Bluegill (Lepomis macrochirus), 96 h): 0.713 - 0.959 mg/l Mortality
Toxicity to fish, Gambusia affinis (fish, fresh water), LC100 = 18 mg/L/24 hours
Toxicity to daphnia and other aquatic invertebrates: Daphnia magna (Crustacea), EC0 = >0.63 mg/L
Toxicity to algae: Anabaena sp. (Algae), EC50 = <0.5 mg/L/18 days/growth rate
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. DISPOSAL INFORMATION

Waste Disposal Methods: Dispose in accordance with all applicable regulations.

14. TRANSPORT INFORMATION

USA (Land, DOT) and Canada (TDG):
UN Number: UN 1490
Proper Shipping Name: Potassium permanganate
Hazard Class: Oxidizer
Packing Group: II
Division: 5.1
Product packaging containing more than 100 pounds
UN Number: UN 1490
Proper Shipping Name: Potassium permanganate, RQ
Hazard Class: Oxidizer
Packing Group: II
Division: 5.1
Additional Info.: If this product is spilled or leaked into the environment, the CERCLA (40 CFR 302.4) reportable quantity is 100 lbs, and requires National Response Center notification within United States of America.
IATA
UN number: UN 1490
Proper Shipping Name: Potassium permanganate
Transport hazard class(es): 5.1
Marine Pollutant: No
Packing group: II

15. REGULATORY INFORMATION

USA:
SARA Section 302 Extremely Hazardous Substances: None of the chemicals in this product have a TPQ.
SARA Codes CAS # 7722-64-7: acute, flammable.
Section 313: This material contains Permanganic permanganate (listed as Manganese), 100%, (CAS# 7722-64-7) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act: No adverse listing.
Clean Water Act: CAS# 7722-64-7 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Canada WHMIS : CLASS C: Oxidizing material. CLASS E: Corrosive solid.

16. ADDITIONAL INFORMATION

Disclaimer:
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Our company provides this Potassium Permanganate SDS information sheet contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Potassium Permanganate MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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